INTEC Chemistry Blog

2.9 Chemical equilibria

Posted by: intechemistry on: September 23, 2010

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7 Responses to "2.9 Chemical equilibria"

hi sir,

[Chemistry Unit 2 June 2010, Section A, Q8]
Why is the answer B, and not C?

Because in answer C, the vertical line representing t(eqm) has the concentration of A and Y changing after that time. It therefore doesn’t correspond to the the definition of eqm.
In answer B, at t(eqm) onwards, the concentrations of X and Y are const.

As far as I can tell, there isn’t anything wrong with the graph other than that.

sir. is the graph for dynamic equilibrium in facer pg 250 correct? it contradicts with the answer for q8, section A, june 2010 unit 2 paper.

My AS level Facer is in my office. Please tell me how you think it contradicts?

The graph given in Facer is similar to the one in quest 8 june 2010 option C. the difference is that the line after the t eqm is a single straight line. But the answer for the question is B. which graph is accepted?

5, Kosher, May 20, 2012 at 6:49 am
Graphs B and C could happen in terms of concentration values during a chemical reaction. However graph C is wrong ONLY because the horizontal line supposedly showing the time at which equilibrium is reached is wrong because after that point, the concentrations of X and Y still change. So Facer could have either graph. It’s not statistically likely that by random chance initial concentrations of X and Y are chosen which results in them having equal concentration at the end of the reaction, hence graphs of type B are usually chosen to describe a system.

sir i think the graph on page 250 is correct. I read the the other source- notes it says the same. and ask to take extra caution on the y-axis (whether its r.o.r or con) ……btw for endothermic reaction the reactants are thermodynamically stable to products whilst the reverse is true for exothermic reaction ryte?

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